Synthetic Metals 85, 1747 (1997) 
 

Magnetic properties of DCNQI salts studied using mSR

F. L. Pratt1,2, P. A. Pattenden2, S. J. Blundell2, K. H. Chow2, Th. Jestädt2, W. Hayes2, R. Kato3, M. Tamura3, H. Sawa3 and Y. Kashimura3
1Muon Sciene Laboratory, The Institute of Physical and Chemical Research (RIKEN), Rutherford Appleton Laboratory, Chilton, Didcot OX11 0OQ, U.K.
2Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, Oxford OX1 3PU, U.K.
3Institute for Solid State Physics, University of Tokyo, Roppongi, Minato-ku, Tokyo 106, Japan

 Abstract. Examples from the (R1,R2-DCNQI)2X family of molecular conductors have been studied using mSR in order to provide information about the microscopic magnetic properties of the various phases. For the fully deuterated dimethyl Cu salt (d8-DMe-Cu) there is a metal-insulator (MI) transition around 80 K and a magnetic transition around 7 K. The muon spin relaxation rate becomes enhanced in the region of the MI transition and below, reflecting the quenching of valence fluctuations and the appearance of localised spins on the Cu sites. A zero field precession signal develops below 7 K as a result of the 3D magnetic ordering of the Cu spins; the field distribution derived from the precession frequency is consistent with the proposed magnetic structure. In addition to the zero field studies, nuclear quadrupolar level crossing resonance between the muon and the imine nitrogen of the DCNQI has been used to study the temparture dependence of the electronic state of the molecular conductor.

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